I was not saying that this new chemistry you're talking about was ruled out. I was just pointing out that you were saying that something was possible without any evidence other than from what are thought to be similar systems. This is a basic hypothesis and should be tested if you're interested in the answer.
As for biophotons, what are you implying when you say that different tissues from different creatures give off different (and extremely weak) amounts of light? Why should this be paid attention to?
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